Quite often, performance specifications for batteries and chargers are based on ideal conditions. Manufacturers carry out battery tests on brand new equipment and in a protected environment, removed from the stress of daily use. In Batteries in a Portable World, Mr. Buchmann observes the battery in everyday life in the hands of the common user. By reading Batteries in a Portable World, you will acquire a better understanding of the strengths and limitations of the battery. You will learn how to prolong battery life; become familiar with recommended maintenance methods and discover ways to restore a weak battery, if such a method is available for that battery type.
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Both the Tesla Model S and Model X electric vehicles get their electrical energy from the cell, a format that also powers laptops. Tesla Motors expects to consume two billion Li-ion cells by Both the Tesla Model S and Model X electric vehicles EV get their electrical energy from the cell, a format that also powers laptops and medical devices.
The cell measures 18mm in diameter and is 65mm long. A cylindrical cell in a metallic case is durable and has a high specified energy capacity , but cylinders are heavy and have a low packaging density in a cluster compared to the prismatic architecture and the pouch pack. A battery pack for a Tesla vehicle deploys over 7, cells, and to get the desired voltage and amperage, the cells are connected in series and parallel. Figures 1 illustrates the popular cell. At 90kWh, the Tesla Model S has the largest battery in an electric car in terms of watt-hours; it also delivers the longest driving range between charges.
A 90kWh battery holds enough energy to provide a typical U. But batteries must be charged and this draws heavily on the grid. They are also expensive; the EV battery alone carries the price tag of an economy car. Lithium ion batteries come in many variations and Tesla chose the high-energy nickel cobalt aluminum chemistry NCA for the S-Model.
Made by Panasonic, the cell is rated at 3,mAh, a specific energy that is slightly higher than most contenders. Other advantages of the NCA are high specific power for exuberant acceleration and long life. The negatives are high cost and a lower safety margin than other Li-ion systems. Figure 2 outlines six of the most important characteristics of a battery in a spider web.
Batteries for the electric powertrain need high loading and a long life, and the NMC is another popular Li-ion system. NMC stands for nickel-manganese-cobalt and is also used in e-bikes, power tools and military and medical devices. The cathode may consist of one-third nickel, one-third manganese and one-third cobalt, but other combinations are also used to satisfy special requirements.
These blends lower the raw material cost due to reduced cobalt content. Figure 3 demonstrates the characteristics of the NMC. Its strength lays in long life and superior safety, but it has a lower capacity than cobalt-based Li-ion systems.
A further tradeoff is the lower nominal voltage of 3. Figure 4 summarizes the attributes of Li-phosphate. Lithium-ion has much improved. Today, high energy-dense cells deliver over 3,mAh and the costs have gone down further. This, however, does not come without compromise. Newer cells are more delicate than older ones and this can affect the cycle count.
A Swiss manufacturer of upscale e-bikes did a comparison on older and newer cells. Then came the 2. It should be noted that the end-capacity of the newer cells is still higher that the older ones; the 3Ah cell retains 1. EV batteries must carry an eight-year warranty. As the battery loses capacity with age, many BMS gradually increases the charging bandwidth to maintain equal driving range.
Once operating at full bandwidth, the battery gets stressed more, reflecting in accelerated performance drop and reduced driving range. Cold temperature causes the performance of all batteries to drop. Bitter cold also makes charging more difficult, especially with Li-ion, as charging is more delicate that discharging.
The ability to use a battery at low temperature does not automatically permit charging under these same conditions.
Carless charging at low temperatures can inflict permanent damage to the battery. Charging too fast at low temperatures could lead to dendrite growth, reflecting in higher self-discharge and compromise safety.
The battery stress is highest at 4. Keeping a lower voltage also protects the battery during cold-temperature charging and some BMS limit the voltage and current accordingly. Many EV batteries include a heating blanket to protect the battery when charging at cold temperature. Energy to heat the blanket is readily available from the grid. EV owners want ultra-fast charging and technology is available to do so.
Although convenient, fast-charging is harmful to the battery. If at all possible, avoid charge times that are less than 90 minutes, or charge rates above 1C. The onboard BMS keeps record of stressful battery events and historic data can work against a warranty claim. This was the response of a large European EV manufacturer when the question of ultra-fast charging came up at a recent EV battery convention in London.
Safety is a further concern, but this applies to all batteries. A one-in, failure triggered the recall of almost six million lithium-ion batteries in Sony, the manufacturer of these cells, said that on rare occasions microscopic metal particles may come into contact with other parts of the battery cell, leading to a short circuit than can cause venting with flame.
Li-ion has improved and the failure rate has been reduced to one-in million. This is reassuring, but the formula of one-in million could cause cells to fail in the batch of two billion that Tesla plans to consume. It is likely that the failure rate has gone down further but caution is in place when storing tons of batteries in one place.
Fires with battery manufacturers and in warehoused storing batteries are common. Relatively little is known when Li-ion batteries are exposed to harsh environmental conditions. Internal shorts and rapid disassembly are of concern, an event that no safety circuit can stop once in progress.
The fault occurs inside the cell and the battery must burn out. The Li-ion battery of Boeing Dreamliner may have failed due to an electric short; the modified battery enclosed in a metal housing will provide a safeguard should a short recur. All batteries are subject to failure and there is also a reported incident where the battery circuit breaker of a Boeing had to be pulled because of an overheating NiCd battery. In the early s, the National Transportation Safety Board reported several battery incidents per year involving the then new nickel-cadmium ship-board battery on airplanes.
Improvements eventually made NiCd safe; this will also happen with Li-ion. Transporting batteries by air remains a concern. There are regulations as to how much metallic or equivalent lithium can be included in an air shipment. Some content may go unregistered and the United Arab Emirates General Civil Aviation Authority found with reasonable certainty that the fire aboard the UPS freighter was caused by a lithium battery. The aircraft went down on September in the Dubai desert about an hour into its flight to Cologne, Germany.
New air cargo containers are being tested with materials that can withstand intense fires for up to four hours, enabling an emergency landing on most flights. The fire-resistant panels of these air cargo containers consist of fibre-reinforced plastic composite that snuffs fire by depriving it of oxygen. A fire is easier to put out in the cabin than in the cargo bay and since January people can no longer pack spare lithium batteries in checked baggage.
See Li-ion travel restrictions. Airlines allow them as carry-on where fire extinguishers are available. A coffee pot served as an extinguishing device of a flaming laptop battery in one incident. Travelers are reminded of how many batteries can be carried on board in portable devices and as spares. This also includes primary lithium batteries and the maximum weights of lithium or equivalent are: 2 grams for lithium batteries. Few consumer products use these primary batteries today.
This amounts to a Wh battery laptop has about 60Wh 25 grams for all Li-ion combined. This amounts to Wh worth of Li-ion batteries. Effective , lithium-based batteries can no longer be carried as cargo in a passenger aircraft.
In addition, Li-ion in cargo must have a state-of-charge of 30 percent. All packages must bear the Cargo Aircraft Only label in addition to other required marks and labels. This limitation does not affect lithium ion batteries packed with or contained in equipment.
While Li-ion is being scrutinized for safety, other chemistries also exhibit problems. Nickel- and lead-based batteries cause fires too, and some are being recalled. Reasons for failure are defective separators resulting from aging, rough handling, excessive vibration and high-temperature.
Examining recorded incidents of transporting batteries by air over a years period reveals that most failures occurred due to inappropriate packaging or handling. Damaged battery packs and electrical shorts due to careless packaging were the main culprits. Most incidents happened at airports or in cargo hubs.
Problem batteries include primary lithium that contains lithium-metal, as well as lead, nickel and alkaline systems, and not just lithium-ion, as is perceived.
Modern consumer products have very few failures involving Li-ion batteries today. Cadex specializes in the design and manufacturing of battery chargers, analyzers and monitoring devices. For more information on batteries, visit www. Request Information Require a custom battery pack? We have years of experience matching battery and charger to improve battery performance and extend service life, Contact Us Today View our Work Here are samples of our custom products developed for various industries.
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BATTERIES IN A PORTABLE WORLD BY ISIDOR BUCHMANN PDF
Batteries in a Portable World: A Handbook on Rechargeable Batteries for Non-Engineers